The host nation will take on Denmark in Sunday's final after a 3-0 victory in Enschede.
Boss Sampson said of his squad afterwards: "Over the last year, they have given absolutely everything to try and help us win this tournament.
"We knew it would be difficult. We were up against the host nation, big crowd, excellent team, very motivated.
"Congratulations to them, they deserve their place in the final and we wish them all the best. The supporters made it a special night for women's football."